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Título : | Thermal behaviour and isothermal kinetics of rhodium(II) acetate. |
Autor : | Carvalho, Cornélio de Freitas Braga, Mauro Mendes Yoshida, Maria Irene Sinisterra, Ruben Dario |
Palabras clave : | Thermal decomposition Isothermal Kinetics Mechanism Rhodium(II) carboxylates |
Fecha de publicación : | 1997 |
Citación : | BRAGA, M. M. et al. Thermal behaviour and isothermal kinetics of rhodium(II) acetate. Thermochimica Acta, v. 296, p. 141-148, 1997. Disponível em: <https://www.sciencedirect.com/science/article/pii/S004060319700021X>. Acesso em: 19 out. 2012. |
Resumen : | The thermal decomposition of solid rhodium(II) acetate was studied by isothermal TG. Kinetic analysis of the isothermal data showed that the complex decomposition in the range 198.0-210.5°C occurs according to a Prout-Tompkins (An) law. The isothermal curves are better fitted using a non-linear least square method. The activation energy found was 16:2.7 kJ tool ~. At temperatures higher than 210.5°C the decomposition is strongly accelerated and no kinetic study was available. |
URI : | http://www.repositorio.ufop.br/handle/123456789/1694 |
ISSN : | 00406031 |
metadata.dc.rights.license: | O periódico Thermochimica Acta concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença 3313091134473. |
Aparece en las colecciones: | DEQUI - Artigos publicados em periódicos |
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ARTIGO_ThermalBehaviourIsothermal.pdf | 320,72 kB | Adobe PDF | Visualizar/Abrir |
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