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Título : Thermal behaviour and isothermal kinetics of rhodium(II) acetate.
Autor : Carvalho, Cornélio de Freitas
Braga, Mauro Mendes
Yoshida, Maria Irene
Sinisterra, Ruben Dario
Palabras clave : Thermal decomposition
Isothermal
Kinetics
Mechanism
Rhodium(II) carboxylates
Fecha de publicación : 1997
Citación : BRAGA, M. M. et al. Thermal behaviour and isothermal kinetics of rhodium(II) acetate. Thermochimica Acta, v. 296, p. 141-148, 1997. Disponível em: <https://www.sciencedirect.com/science/article/pii/S004060319700021X>. Acesso em: 19 out. 2012.
Resumen : The thermal decomposition of solid rhodium(II) acetate was studied by isothermal TG. Kinetic analysis of the isothermal data showed that the complex decomposition in the range 198.0-210.5°C occurs according to a Prout-Tompkins (An) law. The isothermal curves are better fitted using a non-linear least square method. The activation energy found was 16:2.7 kJ tool ~. At temperatures higher than 210.5°C the decomposition is strongly accelerated and no kinetic study was available.
URI : http://www.repositorio.ufop.br/handle/123456789/1694
ISSN : 00406031
metadata.dc.rights.license: O periódico Thermochimica Acta concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença 3313091134473.
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