Thermal behaviour and isothermal kinetics of rhodium(II) acetate.

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Título:	Thermal behaviour and isothermal kinetics of rhodium(II) acetate.
Autor(es):	Carvalho, Cornélio de Freitas Braga, Mauro Mendes Yoshida, Maria Irene Sinisterra, Ruben Dario
Palavras-chave:	Thermal decomposition Isothermal Kinetics Mechanism Rhodium(II) carboxylates
Data do documento:	1997
Referência:	BRAGA, M. M. et al. Thermal behaviour and isothermal kinetics of rhodium(II) acetate. Thermochimica Acta, v. 296, p. 141-148, 1997. Disponível em: <https://www.sciencedirect.com/science/article/pii/S004060319700021X>. Acesso em: 19 out. 2012.
Resumo:	The thermal decomposition of solid rhodium(II) acetate was studied by isothermal TG. Kinetic analysis of the isothermal data showed that the complex decomposition in the range 198.0-210.5°C occurs according to a Prout-Tompkins (An) law. The isothermal curves are better fitted using a non-linear least square method. The activation energy found was 16:2.7 kJ tool ~. At temperatures higher than 210.5°C the decomposition is strongly accelerated and no kinetic study was available.
URI:	http://www.repositorio.ufop.br/handle/123456789/1694
ISSN:	00406031
Licença:	O periódico Thermochimica Acta concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença 3313091134473.
Aparece nas coleções:	DEQUI - Artigos publicados em periódicos

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