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http://www.repositorio.ufop.br/jspui/handle/123456789/11188
Title: | 1D coordination polymer based on copper(II)-containing tetrameric 1,2,3- triazole ligand from click chemistry : magnetic and catalytic properties. |
Authors: | Teixeira, Leonardo César de Moraes Souza, Gilmar Pereira de Fajardo, Humberto Vieira Luz, Sulusmon Cesar Álvarez, Eleuterio Lloret, Francesc Viana, Renato Márcio Ribeiro Rojo Marcos, Francisco Javier Stumpf, Humberto Osório Figueiredo, Rute Cunha Correa, Rodrigo de Souza |
Keywords: | Crystal structure Catalysis |
Issue Date: | 2019 |
Citation: | TEIXEIRA, L. C. de M. et al. 1D coordination polymer based on copper(II)-containing tetrameric 1,2,3- triazole ligand from click chemistry : magnetic and catalytic properties. Inorganica Chimica Acta, v. 489, p. 93-99, abr. 2019. Disponível em: <https://www.sciencedirect.com/science/article/pii/S0020169318318176>. Acesso em: 7 mar. 2019. |
Abstract: | A novel tetrameric tetra[O-((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)]-pentaerythritol (TBTP) has been synthesized using click chemistry strategy. TBTP was characterized and used as ligand to form new Cu(II) complexes, forming 1-D coordination polymers. Two square planar complexes were characterized by single-crystal X-ray diffraction, presenting formula [Cu(TBTP)][Cu(NO3)4] (1) and [Cu(TBTP)](NO3)2 (2). In both structures, a cationic 1-D coordination polymer (CP) has been formed. The CP contain a 1:1 Cu(II)/TBTP ratio with four neutral triazole groups coordinating the Cu(II) center, forming a CuN bonds ranging 1.988(2)–2.001(2) Å. The study of the magnetic properties of compounds 1 and 2 pointed to an antiferromagnetic behavior for both compounds, defined by inter- and intra-chain dipolar interactions among their metallic centers. In addition, the complex 1 was found to be an efficient catalyst for selective oxidation of aniline to azobenzene under mild reaction conditions. |
URI: | http://www.repositorio.ufop.br/handle/123456789/11188 |
metadata.dc.identifier.uri2: | https://www.sciencedirect.com/science/article/pii/S0020169318318176 |
metadata.dc.identifier.doi: | https://doi.org/10.1016/j.ica.2019.02.010 |
ISSN: | 0020-1693 |
Appears in Collections: | DEQUI - Artigos publicados em periódicos |
Files in This Item:
File | Description | Size | Format | |
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ARTIGO_1DCoordinationPolymer.pdf Restricted Access | 3,36 MB | Adobe PDF | View/Open |
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