Heteropoly acid catalysts in Prins cyclization for the synthesis of Florol.

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dc.contributor.authorMeireles, Augusto Luís Pereira de
dc.contributor.authorRocha, Kelly Alessandra da Silva
dc.contributor.authorKozhevnikova, Elena Fedorovna
dc.contributor.authorKozhevnikov, Ivan V.
dc.contributor.authorGusevskaya, Elena Vitalievna
dc.date.accessioned2023-05-22T21:07:24Z
dc.date.available2023-05-22T21:07:24Z
dc.date.issued2021pt_BR
dc.description.abstractH3PW12O40 heteropoly acid supported on SiO2 and its bulk acidic cesium salt Cs2.5H0.5PW12O40 are demonstrated to be highly active and recyclable solid catalysts for Prins cyclization allowing for the clean, high-yielding synthesis of Florol® from isoprenol and isovaleraldehyde. Florol®, a valuable floral odorant employed in a vast variety of commercial products, was obtained in ca. 80 % yield under nearly ambient conditions. Dime- thylcarbonate or diethylcarbonate used as green reaction media, low catalyst loadings and moderate conditions are important features that contribute for the sustainability of the method.pt_BR
dc.identifier.citationMEIRELES, A. L. P. de et al. Heteropoly acid catalysts in Prins cyclization for the synthesis of Florol. Molecular Catalysis, v. 502, artigo 111382, fev. 2021. Disponível em: <https://www.sciencedirect.com/science/article/pii/S2468823120306453>. Acesso em: 11 out. 2022.pt_BR
dc.identifier.doihttps://doi.org/10.1016/j.mcat.2020.111382pt_BR
dc.identifier.issn2468-8231
dc.identifier.urihttp://www.repositorio.ufop.br/jspui/handle/123456789/16619
dc.identifier.uri2https://www.sciencedirect.com/science/article/pii/S2468823120306453pt_BR
dc.language.isoen_USpt_BR
dc.rightsrestritopt_BR
dc.titleHeteropoly acid catalysts in Prins cyclization for the synthesis of Florol.pt_BR
dc.typeArtigo publicado em periodicopt_BR
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