Complete assignment of the 1H and 13C NMR spectra of the tetraisoprenylated benzophenone 15-epiclusianone.
dc.contributor.author | Santos, Marcelo Henrique dos | |
dc.contributor.author | Nagem, Tanus Jorge | |
dc.contributor.author | Braz Filho, Raimundo | |
dc.contributor.author | Lula, Ivana Silva | |
dc.contributor.author | Speziali, Nivaldo Lucio | |
dc.date.accessioned | 2017-06-13T13:33:33Z | |
dc.date.available | 2017-06-13T13:33:33Z | |
dc.date.issued | 2001 | |
dc.description.abstract | An NMR study of 15-epiclusianone, 1-benzoyl-6-hydroxy-14,14-dimethyl-3,5,15-tri(3-methyl-2-butenyl)- bicyclo[3.3.1]non-1-ene-4,6-dione (1), a novel tetraisoprenylated benzophenone isolated from pericarp of fruits of Rheedia gardneriana, is described. In addition to conventional 1D NMR techniques, 2D shiftcorrelated NMR experiments [1H 1H-COSY, 1H 13C-HMQC-1J(C,H), 1H 13C-HMBC-nJ(C,H) (n = 2 and 3) and 1H 1H-NOESY] were used for 1H and 13C chemical shift assignments of this natural product. The 1D 13C NMR spectrum of 1 in the solid state was also obtained. | pt_BR |
dc.identifier.citation | SANTOS, M. H. dos et al. Complete assignment of the 1H and 13C NMR spectra of the tetraisoprenylated benzophenone 15-epiclusianone. Magnetic Resonance in Chemistry, Chichester, v. 39, n.3, p. 155-159, 2001. Disponível em: <http://onlinelibrary.wiley.com/doi/10.1002/mrc.795/full>. Acesso em: 20 mai. 2017. | pt_BR |
dc.identifier.doi | https://doi.org/10.1002/mrc.795 | |
dc.identifier.issn | 1097-458X | |
dc.identifier.uri | http://www.repositorio.ufop.br/handle/123456789/7948 | |
dc.identifier.uri2 | http://onlinelibrary.wiley.com/doi/10.1002/mrc.795/full | pt_BR |
dc.language.iso | en_US | pt_BR |
dc.rights | restrito | pt_BR |
dc.title | Complete assignment of the 1H and 13C NMR spectra of the tetraisoprenylated benzophenone 15-epiclusianone. | pt_BR |
dc.type | Artigo publicado em periodico | pt_BR |