Heteropoly acid catalysts for the synthesis of fragrance compounds from biorenewables : the alkoxylation of monoterpenes.
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2014
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The cesium salt of tungstophosphoric heteropoly acid,
Cs2.5H0.5PW12O40, is an active and environmentally friendly solidacid
catalyst for the liquid-phase alkoxylation of widespread
monoterpenes, such as camphene, limonene, a-pinene, and bpinene.
These reactions provide isobornyl or a-terpenyl ethers,
useful as fragrances, in good to excellent yields. The reactions
are equilibrium-controlled and occur with high catalyst turnover
numbers (TONs) up to 1500–4200 without catalyst leaching.
Heteropoly acid H3PW12O40 also efficiently catalyzes the
alkoxylation of these monoterpenes under homogeneous conditions
with TONs up to 1500–11 300.
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MEIRELES, A. L. P. de et al. Heteropoly acid catalysts for the synthesis of fragrance compounds from biorenewables: the alkoxylation of monoterpenes. ChemCatChem, v. 6, p. 2706 – 2711, 2014. Disponível em: <http://onlinelibrary.wiley.com/doi/10.1002/cctc.201402395/abstract>. Acesso em: 20 mai. 2017.