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Title: Raman scattering study of the high temperature phase transitions of NaTaO3.
Authors: Teixeira, Nayara Gomes
Dias, Anderson
Moreira, Roberto Luiz
Keywords: Dielectric properties
Issue Date: 2007
Citation: TEIXEIRA, N. G.; DIAS, A.; MOREIRA, R. L. Raman scattering study of the high temperature phase transitions of NaTaO3. Journal of the European Ceramic Society, v. 27, n.13-15, p.3683–3686, mar. 2007. Disponível em: <>. Acesso em: 02 jul. 2012.
Abstract: The phase transition sequence of sodium tantalate (NaTaO3) ceramic samples has been investigated by Raman spectroscopy, from room temperature up to 640 ◦C. At room temperature, NaTaO3 shows an orthorhombically distorted perovskite structure belonging to the Pbnm space group. Raman and infrared vibrational spectra at 20 ◦C are in relative good agreement with group theory predictions for this group. At high temperatures, NaTaO3 shows three phase transitions, in the sequence Pbnm (∼450 ◦C) Cmcm (∼560 ◦C) P4/mbm (∼620 ◦C) Pm¯3m. The Raman spectra for the two intermediate high temperature phases showed a decreasing of the number of the active modes, accompanied by band broadening, and were well compatible with structural symmetry increasing at higher temperatures.
ISSN: 09552219
metadata.dc.rights.license: O Periódico Journal of the European Ceramic Society concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3333160050143
Appears in Collections:DEQUI - Artigos publicados em periódicos

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