Please use this identifier to cite or link to this item:
Title: Supramolecular aggregation in new crystals with nonlinear optical properties : 2-aminophenol-HClO4, 3-aminophenol-HClO4 and 4-aminophenol-HClO4.
Authors: Janczak, Jan
Perpétuo, Genivaldo Julio
Keywords: Crystal structure
Issue Date: 2009
Citation: JANCZAK, J.; PERPÉTUO, G. J. Supramolecular aggregation in new crystals with nonlinear optical properties: 2-aminophenol-HClO4, 3-aminophenol-HClO4 and 4-aminophenol-HClO4. Solid State Sciences, v. 11, p. 1576-1581, 2009. Disponível em: <>. Acesso em: 09 mar. 2017.
Abstract: Three new hybrid crystals of 2-aminophenol-HClO4 (2-AP-HClO4,1), 3-aminophenol-HClO4 (3-AP-HClO4, 2) and 4-aminophenol-HClO4 (4-AP-HClO4, 3) were obtained and their crystal structures determined. The 1 crystallises in centrosymmetric space group C2/c of monoclinic system while the other two (2 and 3) crystallise in the non-centro symmetric space groupP21 andP212121, respectively. The oppositely charged units of the crystals, i.e. positively charged 2-APHþ, 3-APHþ and 4-APHþ and ClO4 , interact viaweak Nþ–H/O and O– H/O hydrogen bonds forming 3D-supramolecular network. Relative to KDP the SHG efficiencies are 0.62 for 2 and 0.33 for 3, measured at 1064 nm using the Kurtz–Perry method.
ISSN: 1293-2558
Appears in Collections:DEFIS - Artigos publicados em periódicos

Files in This Item:
File Description SizeFormat 
ARTIGO_SupramolecularAggregationNew.pdf607,17 kBAdobe PDFView/Open    Request a copy

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.