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Title: | Removal of cobalt (II), copper (II), and nickel (II) ions from aqueoussolutions using phthalate - functionalized sugarcane bagasse : mono - and multicomponent adsorption in batch mode. |
Authors: | Ramos, Stela Nhandeyara do Carmo Xavier, Pedrosa Teodoro, Filipe Simões Gil, Laurent Frédéric Gurgel, Leandro Vinícius Alves |
Keywords: | Sugarcane bagasse Adsorption Desorption Metal ion Phthalic anhydride |
Issue Date: | 2016 |
Citation: | RAMOS, S. N. do C. et al. Removal of cobalt (II), copper (II), and nickel (II) ions from aqueoussolutions using phthalate - functionalized sugarcane bagasse: mono - and multicomponent adsorption in batch mode. Industrial Crops and Products, v. 79, p. 116-130, 2016. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0926669015304799>. Acesso em: 16 jun. 2016. |
Abstract: | This study describes, in detail, the chemical modification of sugarcane bagasse with phthalic anhydrideto produce a carboxylate-functionalized sugarcane bagasse (SPA). The optimized modification condi-tions yielded SPA with a percent weight gain of 77.08% and an amount of carboxylic acid groups of 4.76mmol/g. The SPA was characterized by PZC, FTIR, elemental analysis, TGA, and SEM-EDX. An SPA adsor-bent was used to remove Co2+, Cu2+, and Ni2+from aqueous solution in mono- and multicomponentsystems in batch mode. The adsorption kinetics followed a pseudo-second-order model. The adsorptionrate constants assumed the following order: k2,Co2+> k2,Ni2+> k2,Cu2+. Four mono- and multicomponentisotherm models were used to model the adsorption data. Monocomponent data were well described bythe Langmuir model, whereas bicomponent data were well described by the modified extended Lang-muir and P-Factor models. The maximum adsorption capacities (Qmax,mono) for the Langmuir model were0.561, 0.935, and 0.932 mmol/g for Co2+, Cu2+, and Ni2+, respectively. Adsorption in bicomponent systemsrevealed that Cu2+suppressed the adsorption of Co2+and Ni2+, whereas Ni2+suppressed the adsorptionof Co2+. Desorption studies revealed that the SPA adsorbent could be fully desorbed with a 1 mol/L HNO3solution. |
URI: | http://www.repositorio.ufop.br/handle/123456789/6700 |
metadata.dc.identifier.doi: | https://doi.org/10.1016/j.indcrop.2015.10.035 |
ISSN: | 0926-6690 |
metadata.dc.rights.license: | O periódico Industrial Crops and Products concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3898811060759. |
Appears in Collections: | DEQUI - Artigos publicados em periódicos |
Files in This Item:
File | Description | Size | Format | |
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ARTIGO_RemovalCobaltCopper.pdf | 1,69 MB | Adobe PDF | View/Open |
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