Please use this identifier to cite or link to this item: http://www.repositorio.ufop.br/handle/123456789/5126
Title: Phosphotungstic heteropoly acid as efficient heterogeneous catalyst for solvent-free isomerization of a-pinene and longifolene.
Authors: Rocha, Kelly Alessandra da Silva
Dutenhefner, Patricia Alejandra Robles
Kozhevnikov, Ivan V.
Gusevskaya, Elena Vitalievna
Keywords: Isomerization
Terpenes
Acid catalysis
Heteropoly acid
Issue Date: 2009
Citation: ROCHA, K. A. da S. et al. Phosphotungstic heteropoly acid as efficient heterogeneous catalyst for solvent-free isomerization of a-pinene and longifolene. Applied Catalysis. A, General, v. 352, p. 188-192, 2009. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0926860X08006303>. Acesso em: 02 fev. 2015.
Abstract: Silica-supported H3PW12O40 (PW), the strongest heteropoly acid in the Keggin series, is an efficient, environmentally friendly heterogeneous catalyst for the liquid-phase isomerization of a-pinene and longifolene into their more valuable isomers – camphene and isolongifolene, respectively, which are intermediates in the synthesis of expensive fragrances. The reactions occur under solvent-free conditions in the temperature range of 80–100 8C, with low catalyst loadings (0.15–5 wt%) and high turnover numbers (up to 6000 per proton). The catalyst can be easily recovered and reused. No PW leaching is observed in the reaction system.
URI: http://www.repositorio.ufop.br/handle/123456789/5126
metadata.dc.identifier.doi: https://doi.org/10.1016/j.apcata.2008.10.005
ISSN: 0926-860X
metadata.dc.rights.license: O periódico Applied Catalysis A: General concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3581990121031.
Appears in Collections:DEQUI - Artigos publicados em periódicos

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