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http://www.repositorio.ufop.br/jspui/handle/123456789/5093
Title: | Direct decomposition of methane over Ni catalyst supported in magnesium aluminate. |
Authors: | Nuernberg, Giselle De Boit Foletto, Edson Luiz Campos, Carlos Eduardo Maduro de Fajardo, Humberto Vieira Carreño, Neftalí Lenin Villarreal Probst, Luiz Fernando Dias |
Keywords: | Methane decomposition Magnesium aluminate Synthesis |
Issue Date: | 2012 |
Citation: | NUEMBERG, G. D. B. et al. Direct decomposition of methane over Ni catalyst supported in magnesium aluminate. Journal of Power Sources, v. 208, p. 409-414, 2012. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0378775312003977>. Acesso em: 02 fev. 2015. |
Abstract: | In this paper, the results obtained in the methane decomposition reaction promoted by a Ni catalyst supported on MgAl2O4 spinel are presented. The textural properties of the catalyst were investigated by X-ray diffraction (XRD), N2 adsorption/desorption isotherms (BET and BJH methods), thermogravimetric (TGA) and temperature-programmed reduction (TPR) analysis. The influence of the operating conditions employed on the methane decomposition was studied. According to the results, it was found that a N2:CH4 molar ratio of 7:1 and catalyst reduction temperature of 700 ◦C/1 h were the best conditions for methane decomposition. In addition, in the methane decomposition over Ni/MgAl2O4, multiwall carbon nanotubes were formed. |
URI: | http://www.repositorio.ufop.br/handle/123456789/5093 |
metadata.dc.identifier.doi: | https://doi.org/10.1016/j.jpowsour.2012.02.037 |
ISSN: | 0378-7753 |
metadata.dc.rights.license: | O periódico Journal of Power Sources concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3580760328629. |
Appears in Collections: | DEQUI - Artigos publicados em periódicos |
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ARTIGO_DirectDecompositionMethane.pdf | 494,07 kB | Adobe PDF | View/Open |
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