Please use this identifier to cite or link to this item: http://www.repositorio.ufop.br/handle/123456789/4480
Full metadata record
DC FieldValueLanguage
dc.contributor.authorPerpétuo, Genivaldo Julio-
dc.contributor.authorJanczak, Jan-
dc.date.accessioned2015-02-24T18:33:54Z-
dc.date.available2015-02-24T18:33:54Z-
dc.date.issued2012-
dc.identifier.citationPERPÉTUO, G. J.; JANCZAK, J. Hydrogen-bonding network in the crystal of bis[1-(diaminomethylene)thiouron-1-ium] oxalate. Journal of Molecular Structure, v. 1007, p. 74-80, 2012. Disponível em: <http://www.sciencedirect.com/science/article/pii/S002228601100812X>. Acesso em: 19 fev. 2015.pt_BR
dc.identifier.issn0022-2860-
dc.identifier.urihttp://www.repositorio.ufop.br/handle/123456789/4480-
dc.description.abstractThe single crystals of bis[1-(diaminomethylene)thiouron-1-ium] oxalate were grown using a solution growth technique. The compound crystallises in the centrosymmetric C2/c space group of the monoclinic system. The conformation of the 1-(diaminomethylene)thiouron-1-ium cation is not strictly planar, but twisted. Both arms of the cation are oppositely rotated by 5.0(1)_ around the C–N bonds involving the central N atom. The centrosymmetric oxalate(2-) anion is planar. The arrangement of oppositely charged components, i.e. 1-(diaminomethylene)thiouron-1-ium cations and oxalate(2-) anions in the crystal is mainly determined by ionic and hydrogen bonding interactions forming three-dimensional network. The compound was also characterised by the FT-IR and Raman spectroscopy. The characteristic bands of the NH2, C=S and COO_ groups as well as of C–N–C, N–C–N and C–COO skeletal groups are discussed.pt_BR
dc.language.isoen_USpt_BR
dc.subjectCrystal structurept_BR
dc.subjectHydrogen bondspt_BR
dc.subjectVibrational spectroscopypt_BR
dc.titleHydrogen-bonding network in the crystal of bis[1-(diaminomethylene)thiouron-1-ium] oxalate.pt_BR
dc.typeArtigo publicado em periodicopt_BR
dc.rights.licenseO periódico Journal of Molecular Structure concede permissão para depósito do artigo no Repositório Institucional da UFOP. Número da licença: 3566050626691.pt_BR
dc.identifier.doihttps://doi.org/10.1016/j.molstruc.2011.10.020-
Appears in Collections:DEFIS - Artigos publicados em periódicos

Files in This Item:
File Description SizeFormat 
ARTIGO_HydrogenBondingNetwork.pdf915,25 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.