Please use this identifier to cite or link to this item: http://www.repositorio.ufop.br/jspui/handle/123456789/14219
Title: A bifunctional catalyst based on Nb and V oxides over alumina : oxidative cleavage of crude glycerol to green formic acid.
Authors: Oliveira, Henrique dos Santos
Oliveira, Luiz Carlos Alves de
Chagas, Poliane
Sangiorge, Daniel Lara
Portilho, Marcio de Figueiredo
Siqueira, Kisla Prislen Félix
Hensen, Emiel J. M.
Issue Date: 2020
Citation: OLIVEIRA, H, dos S. et al. A bifunctional catalyst based on Nb and V oxides over alumina: oxidative cleavage of crude glycerol to green formic acid. New Journal of Chemistry, v. 44, p. 8538-8544, 2020. Disponível em: <https://pubs.rsc.org/en/content/articlelanding/2020/nj/d0nj00384k>. Acesso em: 10 jun. 2021.
Abstract: A bimetallic vanadium and niobium oxide catalyst using alumina as support was developed for the conversion of crude glycerol from biodiesel production into formic acid. The high dispersion of the active oxide phase combined with the presence of acid and redox active centers resulted in a high glycerol conversion (490% for 25 h) with a good selectivity for formic acid (B55%). This process is the first example of a heterogeneous liquid-phase process for the conversion of crude glycerol to formic acid, which is an important chemical intermediate currently derived from petroleum feedstock.
URI: http://www.repositorio.ufop.br/jspui/handle/123456789/14219
metadata.dc.identifier.uri2: https://pubs.rsc.org/en/content/articlelanding/2020/nj/d0nj00384k
metadata.dc.identifier.doi: https://doi.org/10.1039/D0NJ00384K
ISSN: 1369-9261
Appears in Collections:DEQUI - Artigos publicados em periódicos

Files in This Item:
File Description SizeFormat 
ARTIGO_BifunctionalCatalystBased.pdf
  Restricted Access
2,88 MBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.