Navegando por Autor "Knupp, Vagner Fernandes"
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Item Modeling and optimization of the pyrolysis oil production process from polypropylene for the production of aviation kerosene.(2022) Santos, Heraclito Alexandre dos; Santos, Igor José Boggione; Quintão, Cristiane Medina Finzi; Knupp, Vagner Fernandes; Lofrano, Renata Carolina Zanetti; Oliveira, Eliane Cristina de; Samanamud, Gisella Lamas; Amaral, Mateus de Souza; França, Alexandre Bôscaro; Pereira, Mariana Arruda; Silva, Matheus Teixeira Araújo; Loures, Carla Cristina Almeida; Carneiro, Mozart dos Santos; Ponciano, Jéssica Amaral Pereira; Naves, Luzia Lima Rezende; Naves, Fabiano LuizOne of the greatest challenges in the world is in the fnal disposal of plastics in order to reduce the efect of its polluting potential. Thus, the application of pyrolysis processes in generating products of interest such as fuel oils can be part of the solution. In addition to reducing greenhouse gas emissions to the atmosphere, oil can enter the supply chain after the cracking process in petrochemical industries. In this context, this work used statistical modeling of the response surface linked to the normal boundary intersection algorithm, aiming at a higher yield of oil production and major selectivity of recycled polypropylene pyrolysis. From the analysis of the mechanisms proposed in the literature with the modeling and optimization in this work, it was possible, from a kaolin mass of 9.12 g and a heating ramp of 19.37 °C/min, to obtain higher percentages of aviation kerosene as well as a satisfactory performance.Item Stereochemistry of 16α-hydroxyfriedelin and 3-oxo-16-methylfriedel-16-ene established by 2D NMR spectroscopy.(2009) Duarte, Lucienir Pains; Miranda, Roqueline Rodrigues Silva de; Rodrigues, Salomão Bento Vasconcelos; Silva, Grácia Divina de Fátima; Vieira Filho, Sidney Augusto; Knupp, Vagner FernandesFriedelin (1), 3β-friedelinol (2), 28-hydroxyfriedelin (3), 16α-hydroxyfriedelin (4), 30-hydroxyfriedelin (5) and 16α,28-dihydroxyfriedelin (6) were isolated through fractionation of the hexane extract obtained from branches of Salacia elliptica. After a week in CDCl3 solution, 16α-hydroxyfriedelin (4) reacted turning into 3-oxo-16- methylfriedel-16-ene (7). This is the first report of a dehydration followed by a Nametkin rearrangement of a pentacyclic triterpene in CDCl3 solution occurring in the NMR tube. These seven pentacyclic triterpenes was identified through NMR spectroscopy and the stereochemistry of compound 4 and 7 was established by 2D NMR (NOESY) spectroscopy and mass spectrometry (GC-MS). It is also the first time that all the 13C-NMR and 2D NMR spectral data are reported for compounds 4 and 7.