DEGEO - Artigos publicados em periódicos
URI Permanente para esta coleção
Navegar
Submissões Recentes
Item Modelagem espacial dos locais de ocorrência de paleotocas nas Serras do Gandarela e do Curral, Quadrilátero Ferrífero - MG.(2022) Assis, Driele Antunes de; Castro, Paulo de Tarso AmorimO geossistema ferruginosos do Quadrilátero Ferrífero (QFe) constantemente envolve cenários de disputa entre exploração mineral e conservação ambiental. Estudos recentes em cavernas da região, atestaram que duas delas tratam-se de paleotocas. Em litologia ferruginosa, foram verificados inicialmente no Vale do Rio Peixe Bravo (VPB), norte de Minas Gerais. No QFe, os únicos registros encontrados estão situados na Serra do Gandarela e na Serra do Curral, escavados no contato canga/saprolito. Especialmente a paleotoca do Gandarela, está ameaçada pela mineração. O objetivo deste trabalho foi discriminar áreas-alvo potenciais de novas ocorrências de paleotocas no QFe a partir da comparação das características geomorfológicas e geológicas das áreas de ocorrência destes icnofósseis tanto no QFe, quanto em outros geossistemas ferruginosos. Os procedimentos metodológicos envolveram a técnica Delphi e o uso de geoprocessamento na construção de mapas temáticos e elaboração de um mapa de potencialidade de ocorrências. A análise permitiu identificar que as duas paleotocas e a maioria das cavidades naturais registradas em zonas de alto potencial, ocorrem em rochas do Grupo Itabira (itabiritos). Por serem áreas de grande interesse da mineração, tornam-se prioritárias à investigação e caracterização, de modo a garantir a integridade de possíveis registros paleontológicos.Item Metabarcoding of soil fungal communities in rupestrian grassland areas preserved and degraded by mining : implications for restoration.(2023) Figueiredo, Maurílio Assis; Silva, Thamar Holanda da; Pinto, Otavio Henrique Bezerra; Leite, Mariangela Garcia Praça; Oliveira, Fábio Soares de; Messias, Maria Cristina Teixeira Braga; Rosa, Luiz Henrique; Câmara, Eduardo Aguiar Saraiva; Lopes, Fabyano Alvares Cardoso; Kozovits, Alessandra RodriguesRupestrian grasslands are vegetation complexes of the Cerrado biome (Brazilian savanna), exhibiting simultaneously great biodiversity and important open-pit mining areas. There is a strong demand for the conservation of remaining areas and restoration of degraded. This study evaluated, using next-generation sequencing, the diversity and ecological aspects of soil fungal communities in ferruginous rupestrian grassland areas preserved and degraded by bauxite mining in Brazil. In the preserved and degraded area, respectively, 565 and 478 amplicon sequence variants (ASVs) were detected. Basidiomycota and Ascomycota comprised nearly 72% of the DNA, but Ascomycota showed greater abundance than Basidiomycota in the degraded area (64% and 10%, respectively). In the preserved area, taxa of different hierarchical levels (Agaromycetes, Agaricales, Mortierelaceae, and Mortierella) associated with symbiosis and decomposition were predominant. However, taxa that colonize environments under extreme conditions and pathogens (Dothideomycetes, Pleoporales, Pleosporaceae, and Curvularia) prevailed in the degraded area. The degradation reduced the diversity, and modified the composition of taxa and predominant ecological functions in the community. The lack of fungi that facilitate plant establishment and development in the degraded area suggests the importance of seeking the restoration of this community to ensure the success of the ecological restoration of the environment. The topsoil of preserved area can be a source of inocula of several groups of fungi important for the restoration process but which occur in low abundance or are absent in the degraded area.Item Spatial distribution of chemical elements in the surface sediments of a tropical estuary in north-eastern Brazil.(2022) Pereira, Monise da Silva; Santana, Carolina Oliveira de; Gonzalez Pacheco, Mauricio; Jesus, Taíse Bomfim de; Francos, Marcos; Castro, Paulo de Tarso Amorim; Nolasco, Marjorie Csekö; Corvacho Ganahin, Oscar; Carneiro, Luanna Maia; Dourado, Gilson Barbosa; Hadlich, Gisele Mara; Bogunovic, IgorThe high socioeconomic importance of estuarine environments is contributing to their continuous and increasing settlement by human populations and a growing negative impact on those sensitive habitats. Considering the natural importance of estuarine regions, this study aimed to quantify and spatialize the distribution of the chemical elements iron (Fe), aluminium (Al), manganese (Mn), vanadium (V), barium (Ba), zinc (Zn), copper (Cu), lithium (Li), cobalt (Co), chromium (Cr), nickel (Ni), lead (Pb) and arsenic (As) and produce a potential risk assessment from the surface sediments along the extent of the Serinha ́em Estuary, Bahia, Brazil, in order to evaluate the environmental quality of the estuary. The mean concentrations of the chemical elements followed the order: Fe > Al > Mn > Ba > Zn > V > Cr > As > Pb > Co > Li > Cu > Ni. Through analysis using the geo- accumulation index, the concentrations of the chemical elements were determined to reflect the local lithology and not the influence of human activities for all the elements, with the exception of Ba, the enrichment of which came from Camamu Bay. The chemical elements in the sediments do not pose a risk to the local biota or the human population. The distribution maps revealed a tendency for the accumulation of higher concentrations of elements in some sectors of the channel. This study can be used in the future as a complete profile of the background concentrations of the studied elements in the sediments, aiding in the continuity of monitoring actions.Item Ferruginous duricrusts associated with diamond occurrences in the Diamantina Plateau, south Espinhaço Range, Brazil.(2021) Milagres, Alcione Rodrigues; Oliveira, Fábio Soares de; Varajão, Angélica Fortes Drummond Chicarino; Varajão, César Augusto ChicarinoMacromorphological and micromorphological characterization of the alteration facies associated with geomorphological studies are of great importance for understanding the genesis and evolution of ferruginous duricrusts. The study of the ferruginous duricrusts in the Diamantina Plateau (Southern Espinhaço Range, Minas Gerais), a region known worldwide for hosting important diamond deposits, was based on the characterization of the faciological variations of representative alteration profiles. The morphometric indexes of the area, macromorphological description of the profiles, and sampling for micromorphological and mineralogical analyzes were carried out to assist in the understanding of the landforms. The results show that the ferruginous duricrusts occur preferentially in the plateaus and high slopes, with the Sopa-Brumadinho Formation as substrate. Two types of ferruginous duricrust have been identified. Type 1 is characterized as a platy duricrust developed from a saprolite of hematitic phyllite with a ferruginous banded structure. Type 2 is characterized by a massive duricrust typically lateritic that overlaps a nodular and mottled facies, originated from a saprolite of hematitic phyllite with a diffuse distribution of opaque minerals. This phyllite is one of the rocks that occur with the diamond host rocks in the old mines of the region. Both types of ferruginous duricrusts formed by relative accumulation evolve into fragmentary facies and the soil. Locally, in discordant contact, occurs a concretionary duricrust, characterized by an absolute iron accumulation mechanism.Item Amphimedon viridis marine sponge as metal bioindicator for Al, Ba, Cr, Fe and Mn.(2022) Moreira, Ronan Pereira Garcias; Krohling, Werther; Ferreira Júnior, Paulo Dias; Abreu, Adriana Trópia de; Nalini Júnior, Hermínio Arias; Schmitt, Elisângela Flávia Pimentel; Coutinho, Silvia Cruz Goes; Endringer, Denise CoutinhoBACKGROUND: Bivalves, oysters, and mussels are accepted as biological indicators for marine pollutants. Heavy metals biomonitoring on the environment was this study objective using A. viridis compared with Perna perna (mollusk bivalve). The area studied included Ilha Pituã in Vila Velha – ES and Ilha do Boi and Camburi Garden Beach in Vitoria - ES. METHODS: The sample collection comprised seawater, mussel (P. perna) and sponge (A. viridis). Al, As, Ba, Cr, Cu, Fe, Pb, Mn, K, Ti and Zn were analyzed using ICP OES. RESULTS For metal studied Al, Ba, Cr, Fe and Mn presented greater accumulation in A. viridis than in P. perna. The metal concentrations detected in seawater, sponge, and mussel could be related using PCA with 79.26% total variance demonstrating that A. viridis bioaccumulated more metals than P. perna. CONCLUSION: Sponge metal accumulation reflected not only spatial metal variation but also seasonal changes.Item Peritidal microbialites in the upper Araras Group : Morphotypes, potential preservation and the relation with the Ediacaran-Cambrian unconformity in the Araras-Alto Paraguai Basin, southern Amazon Craton.(2022) Romero, Guilherme Raffaeli; Santos, Renan Fernandes dos; Nogueira, Afonso César Rodrigues; Rudnitzki, Isaac Daniel; Fairchild, Thomas RichThe Proterozoic biosphere was dominated by shallow-marine and intertidal bacterial biota, as evident from a robust record of microbialites in carbonate rocks. The lower Ediacaran successions in the southeastern Amazon Craton, Brazil represented by carbonates rocks of the Araras Group, record excellent occurrences of microbialites implying significant evidence for shallow marine colonization post-Snowball Earth Events (∼635 Ma). Microbialites occur at the lower and upper units of this group -Mirassol D'Oeste and Nobres, respectively with the lower associated to the Marinoan glaciation event. The upper unit, Nobres Formation, is here described with outcrop-based facies analysis discontinuously exposed in the Araras-Alto Paraguai basin. This allowed the paleoenvironmental reconstructions of the carbonate peritidal settings, organized in tidal flats and sabkha meter-scale cycles. Fifteen levels of microbialites have been described, with 4 morphotype associations. These microbialites colonized upper tidal flat zones forming stromatolite deposits of bulbous domes, stratiform, pseudo-columnar, and “cerebroid” forms. The recurrent cyclicity indicates a residence time of hydrodynamic and climatic variations for a long time producing minimum morphological changes without any decline evidence. In addition, no metazoan competition was observed in these strata. The siliciclastic inflow observed in the top of Nobres Formation is interpreted as seasonal variations that imprint turbidity in the shallow waters causing a diversification of the morphology of microbialites. The microbialite record in the Nobres Formation do not show any evolutionary trend or apparent decline, that has been attributed to the evolution of substrate-modifying metazoans, but suggest a continuous record truncated by the Ediacaran-Cambrian unconformity found at the upper portion of the Araras Group.Item Human impacts outpace natural processes in the Amazon.(2023) Albert, James S.; Carnaval, Ana Carolina Oliveira de Queiroz; Flantua, Suzette G. A.; Lohmann, Lúcia Garcez; Ribas, Camila Cherem; Gonçalves, Douglas Riff; Carrillo, Juan D.; Fan, Ying; Figueiredo, Jorge de Jesus Picanço de; Guayasamin, Juan Manuel; Hoorn, Carina; Melo, Gustavo Henrique Coelho de; Nascimento, Nathália de Oliveira; Nobre Quesada, Carlos Alberto; Ulloa, Carmen Ulloa; Val, Pedro Fonseca de Almeida e; Arieira, Julia; Encalada Romero, Andrea Carolina; Nobre, Carlos AfonsoAmazonian environments are being degraded by modern industrial and agricultural activities at a pace far above anything previously known, imperiling its vast biodiversity reserves and globally important ecosystem services. The most substantial threats come from regional deforestation, because of export market demands, and global climate change. The Amazon is currently perched to transition rapidly from a largely forested to a nonforested landscape. These changes are happening much too rapidly for Amazonian species, peoples, and ecosystems to respond adaptively. Policies to prevent the worst outcomes are known and must be enacted immediately. We now need political will and leadership to act on this information. To fail the Amazon is to fail the biosphere, and we fail to act at our peril.Item Geochemical multifractal modeling of soil and stream sediment data applied to gold prospectivity mapping of the Pitangui Greenstone Belt, northwest of Quadrilátero Ferrífero, Brazil.(2023) Ribeiro, Brenner Otávio Luiz; Barbuena, Danilo; Melo, Gustavo Henrique Coelho deGeochemical mapping has become essential to prospective assessments in both brownfield and greenfield exploration targeting. During the last two decades, several techniques have been applied to the identification of mineralization's geochemical signature. Among these techniques, Hierarchical Clustering (HC) and Principal Component Analysis (PCA) have been widely used. Other techniques, like Multifractal Spectrum (MS) and Local Singularity Mapping (LSM), are efficient in the generation of models suitable to determine the type of database statistical distribution and mapping zones of geochemical enrichment and depletion. We combined these techniques for soil and stream sediment geochemistry and generated two prospective geochemical models for the gold deposits from the Pitangui Greenstone Belt (PGB), located at northwest of Quadrilátero Ferrífero – Brazil. The results of PCA and HC showed a geochemical association of As-Bi-Mo-Sb with gold mineralization in the PGB. According with descriptive statistical analysis, these elements do not display normal or log-normal statistical distribution, which allowed the application of multifractal models on the geochemical mapping. MS technique revealed that all elements associated with gold have a multifractal distribution. In addition, geochemistry data shows that high contents of elements measured in the stream sediment analysis displays greater dispersion when compared to elements of soil geochemistry data, due to their mobility in environmental conditions. We used LSM technique to map geochemical enrichment of the elements associated with gold. The maps were evaluated using the Ground Truth Analysis (GTA) and the results showed a good performance in the identification of prospective zones. The anomalies identified in both geochemical maps showed a strong correlation between geochemical enrichment zones and geological factors that favors gold mineralization. These results bring a new perspective on the distribution of geochemical anomalies using, for the first time, the multifractal geochemical modeling on the PGB. The geochemical maps point to new targets for mineral exploration and contribute significantly for the prospective models of the region.Item The hydrothermal evolution of the Alvo Açaí Cu (Au, Mo) skarn deposit, Carajás Province, Brazil.(2023) Fernandes, Kamila Gomes; Xavier, Roberto Perez; Moreto, Carolina Penteado Natividade; Melo, Gustavo Henrique Coelho de; Boyce, Adrian JosephThe Alvo Açaí Cu (Au, Mo) skarn deposit forms part of several poorly explored copper deposits in the western sector of the Carajás province in Brazil. Here, a 2.86 Ga metasyenogranitic basement and a 2.71 Ga quartzite of the Liberdade Group are crosscut by diabase and granitic pegmatite dikes in the deposit area. The sequence of hydrothermal alteration at Alvo Açaí is marked by (1) early pervasive calcic-sodic alteration (hastingsite- albite) and (2) potassic iron alteration (biotite-almandine-grunerite) overprinted by (3) silicification (quartz), (4) prograde (grossular-hedenbergite), and (5) retrograde (actinolite-biotite-epidote) skarn stages. Late per- vasive chloritization along with epidote-calcite veinlets crosscut the previous alteration zones. The main stage of copper mineralization (I) is spatially and temporally related to the retrograde skarn alteration for which three chalcopyrite-bearing mineral assemblages are distinguished on the basis of textural relationships and mineral associations: (1) actinolite-chalcopyrite-pyrrhotite-pyrite-magnetite-molybdenite, (2) biotite-chalcopy- rite-pyrite-magnetite, and (3) epidote-pyrite-chalcopyrite-sphalerite. Minor chalcopyrite occurs along rare late- stage epidote-calcite veinlets (mineralization II). The evolution of a single hot H2O-NaCl-CaCl2–dominated magmatic fluid of moderate salinity (22.8–28.6 wt % NaCl + CaCl2 equiv) toward a cooler H2O-NaCl fluid, with likely variable amounts of FeCl2, MgCl2, and KCl of low to moderate salinity (0.1–33.2 wt % NaCl equiv). Fluid evolution as a result of progressive crystallization of the granitic pegmatite was likely the trigger for mineraliza- tion I as supported by calculated δ18OH2 O values from retrograde quartz. The chalcopyrite and pyrite δ34S values (–1.5, –1.1, and –0.7‰) point to a magmatic origin for the sulfur, which was most probably leached from sur- rounding igneous host rocks. The evolution of the Alvo Açaí deposit encompasses the development of the first copper skarn mineralization recognized in the Carajás province.Item Uplifting mountains and shaking deserts : volcano-tectonic earthquakes revealed by soft-sediment-deformation structures in Upper Cretaceous aeolian deposits.(2023) Alessandretti, Luciano; Warren, Lucas Veríssimo; Varejão, Filipe Giovanini; Rassi, Raul; Santos, Mauricio Guerreiro Martinho dos; Silva, Mariana N. M.; Honorato, Fernando Resende; Estrada, Michele Jessica Teixeira; Cunha, João V. O.During the last stages of Gondwana fragmentation, large regions of the newly formed South American continent were covered by extensive deserts. Some parts of this continental landmass were synchronously affected by pronounced tectonism and magmatism, which were responsible for reshaping the regional topography. In this context, the southwestern part of the Sanfranciscana Basin in central Brazil is a key area for understanding this particular period in the geodynamic evolution of the South American continent. Aeolian deposits of the Posse Formation in the basin occur in direct association with volcanic rocks of the Upper Cretaceous Mata da Corda Group. Here, we report evidence of synsedimentary magmatism in direct association with soft-sediment-deformation structures, including flame structures, load casts and pseudonodules, water-escape structures, convolute lamination, faults, breccias, and clastic dikes, developed exclusively in aeolian sandstone and siltstone facies. The deformation features are interpreted as indicative of liquefaction, fluidization, and brittle behavior of the loose to partially lithified, wet sandy–silty sediments. The Late Cretaceous aeolian sedimentation is contemporaneous with the uplift of the Parana ́ıba High and associated magmatism in the Minas–Goia ́s Alkaline Province. In this context, these significant volcano-tectonic activities are considered to have triggered ductile to brittle deformation in the reported aeolian deposits.Item Adsorption of gaseous elemental mercury on soils : influence of chemical and/or mineralogical characteristics.(2019) Montoya, Juan Andres; Lena, Jorge Carvalho de; Windmoeller, Claudia CarvalhinhoGaseous elemental Hg is stable enough to be transported over long distances. Some of the most important sources of Hg in the atmosphere are artisanal gold mining activities and forest fires. Both of these sources are particularly prevalent in the Amazonia region. Information regarding the capacity of soils for retaining Hg transported by the atmosphere is very important for understanding the metal cycle in the environment. The aim of this work was to study gaseous elemental Hg adsorption in soils with different physical and chemical characteristics. For this purpose, soils from different regions in Brazil and Colombia influenced or possibly influenced by gold mining activities and forest fires were studied. Hg adsorption tests were conducted by exposing soil samples to a gaseous elemental Hg atmosphere for 144 h. The total Hg concentration (THg) and Hg oxidation states were monitored using a direct Hg analyzer. Sample characterization analyses were performed. THg values obtained before the adsorption tests were 43–413 and 144–590 µg kg−1 for grain size fractions below 2 and 0.063 mm, respectively. The predominant species found was Hg2+, with abundance levels from 68% to 99%. The results show a wide range of enhanced Hg retention capacities among the samples, ranging from 13 to 2236 times the initial concentration, and the speciation results demonstrate a decrease in the oxidized species range, from 21% to 78%. The statistical analysis indicated the importance of Mn-bearing minerals for the processes of adsorption/oxidation of gaseous elemental Hg in soils. These results contribute to the elucidation of the processes that occur with Hg at the soil/atmosphere interface and may help to explain the high concentrations of Hg found in Amazonian soils where no gold mining activities are practiced.Item Native grass sod and plug production as an alternative technique to restore neotropical rupestrian grassland after mining.(2023) Figueiredo, Maurílio Assis; Messias, Maria Cristina Teixeira Braga; Leite, Mariangela Garcia Praça; Kozovits, Alessandra RodriguesDespite the importance of grasses in the structure and functioning of tropical grasslands, there is still a lack of efficient and economically viable techniques to produce and introduce grasses in restoration projects. Here, we evaluated the sod and plug-plant production and planting of a native grass from Brazilian rupestrian grasslands, Sporobolus metallicolus, in a post-bauxite mining. To produce the sod, we used post-mining substrate and its mixture with commercial substrate. Then, we sowed 270 seeds of S. metallicolus on a 4-cm layer of substrate in 144-cm2 trays. Eighty days after sowing, we subdivided the contents of each tray (substrate + plant) into 4 × 3–cm plug-plants. Plug-plants were planted in the degraded area with and without the incorporation of litter from an adjacent conserved rupestrian grassland. We also evaluated the cost of production of each plug-plant. The mixture of substrates provided greater plant growth and rooting, obtaining plug-plants with an average of 13 individuals, dry mass of 270 mg, and estimated cost of US$ 0.0045. In the degraded area, the addition of litter increased shoot biomass gain. Plant survival was 100% with and without litter addition and the plants started seed dispersal at 7 months after planting. The production of S. metallicolus plugs with the mixed substrate and the growth of plants in the post-mined area showed promising results and reduced costs, indicating technical and financial feasibility. The presented techniques can be an option for introducing grasses in degraded areas and optimize the use of seeds.Item The rise and fall of the giant stromatolites of the Lower Permian Irati Formation (Paraná Basin, Brazil) : a multi-proxy based paleoenvironmental reconstruction.(2022) Antunes, Gonçalo Cruz; Warren, Lucas Veríssimo; Okubo, Juliana; Fairchild, Thomas Rich; Varejão, Filipe Giovanini; Uhlein, Gabriel Jubé; Inglez, Lucas; Poiré, Daniel Gustavo; Rumbelsperger, Anelize Manuela Bahniuk; Simões, Marcello GuimarãesGiant stromatolites are meter-scale laminated carbonate biosedimentary deposits formed by the action of benthic microbiota under very specific conditions. Although occurrences of giant stromatolites are relatively common in Precambrian deposits, the Phanerozoic record is still sparse. Here, we carried out an integrated analysis of the Lower Permian Santa Rosa de Viterbo giant stromatolite field, developed in a mixed carbonate-siliciclastic depositional system within a restricted intracontinental basin (Irati Formation, Paran ́ a Basin, Brazil). Using available and new descriptions of stromatolite morphology and associated facies, we applied a multi-proxy approach based upon sedimentological, paleontological, geochemical, and isotopic data to develop a detailed paleoenvironmental model for this particular occurrence. The NE-SW elongated giant stromatolites – of >3 m in height, > 7 m in length, and > 1 m wide – have variable external shape and internal morphology, indicating changing growth strategy due to variations in the hydrodynamic conditions, bathymetry, and terrigenous input. Increasing δ13C values towards the top of the succession are related to intense microbial activity, increased nutrient supply, and enhanced primary productivity, with the higher δ13C values matching the global Permian seawater signal. Y/Ho and La/La* ratios indicate a less restricted setting towards the top of the succession, which is consistent with the increasing water depth recorded by the stromatolite morphology. The combination of smooth lamination, exclusively coccoidal microbial community, and fossil content, point to deposition under high (possibly hyper) salinity conditions for most of the succession. Our data suggests that the existence of stressful conditions (i.e., strong currents and high salinity) protected the benthic microbial communities from predation and favored EPS production, generating the ideal conditions for the growth of giant stromatolites, a very uncommon situation in the Phanerozoic.Item Late Permian siliceous hot springs developed on the margin of a restricted epeiric sea : insights into strata-confined silicification in mixed siliciclastic‐carbonate successions.(2022) Varejão, Filipe Giovanini; Warren, Lucas Veríssimo; Alessandretti, Luciano; Rodrigues, Mariza Gomes; Riccomini, Claudio; Assine, Mario Luis; Cury, Leonardo Fadel; Faleiros, Frederico Meira; Simões, Marcello GuimarãesHot springs are sources of carbonate minerals in modern settings; however, few fossil structures are recorded in successions older than the Quaternary due to their enhanced erosional potential. >4500 siliceous mounds are recognized in a well-defined level from the upper part of the Permian Teresina Formation (Parana ́ Basin, SE Brazil). Additionally, a new mound level is here reported for the first time about 15 m below the main occur- rence. Remarkable lithological, mineralogical, paleontological and geochemical features characterize the mounds of both levels, pointing to a hydrothermal origin. Therefore, these structures are here called as hot springs. These were originated subaerially, on the margins of a closing epeiric sea developed on a large intra- continental sag basin. Hydrothermal fluids were sourced from deep circulating basin waters that erupted through intraplate deep-rooted faults. Our data suggests that these hot springs were active during distinct cycles of base level variations. Strata-confined silicification was enhanced during periods of high evaporation and hydrother- mal exudation. Finally, the vertical and lateral facies associations of the Permian hot spring succession are compared with modern sites, and implications for the recognition of syn-depositional hydrothermally precipitated silica in ancient sedimentary basins are discussed.Item High-resolution taphonomy and sequence stratigraphy of internally complex, bakevelliid-dominated coquinas from the Aptian Romualdo formation, Araripe Basin, NE Brazil.(2022) Rodrigues, Mariza Gomes; Varejão, Filipe Giovanini; Matos, Suzana Aparecida; Fürsich, Franz Theodor; Warren, Lucas Veríssimo; Assine, Mario Luis; Simões, Marcello GuimarãesThe Aptian Romualdo Formation (Araripe Basin, NE Brazil) was deposited in a restricted epeiric sea, during the opening of the South Atlantic Ocean, with a coeval record to that in the Brazilian Pre-Salt succession. The upper part of the Romualdo Formation encompasses the Highstand Systems Tract of a third-order stratigraphic sequence, and contains shell beds interbedded with shale, siltstone, and fine-grained sandstone. Based on distinct taphonomic features (shell sorting, fragmentation, abrasion, rounding, and orientation), sedimentological criteria (shell abundance, type of matrix, sedimentary structures, and presence/absence of quartz grains), and stratigraphic attributes (bed thickness, geometry, contacts), the paleoenvironmental conditions and the bed-by-bed accumulation history of the coquinas is disentangled. Eight carbonate microfacies were recognized, including ostracod carbonate mudstone, bivalve-gastropod wackestone, gastropod-bivalve packstone, bivalve-gastropod grainstone, bivalve-gastropod floatstone, bivalve-gastropod rudstone, bakevelliid floatstone, and bakevelliid rudstone, which are organized in six, cm-thick shell concentrations. Mudstone and wackestone facies mark the settling of carbonate muds without significant bottom currents and wave action, probably below storm wave base, whereas packstone, floatstone, and rudstone, with fragmented, rounded, and oriented shells, were deposited in agitated waters, between the fair-weather and the storm wave bases. Ripple cross-laminated grainstone is interpreted as high-energy facies deposited above fair-weather wave base. The shell beds are internally complex and consist of cm-scale alternations of microfacies differing in packing, sorting, and composition. They tend to fine upwards within dm-thick shell beds, generating shallowing-upward facies sequences. The concentrations, the uppermost one with in situ bakevelliid shells in the top, record high-frequency base level oscillations influenced by eustasy and climate changes. These bioclastic accumulations originated by the superposition of sedimentologic and primary biologic processes (e.g., post-deposition meiofaunal bioturbation). The cm-thick, low-diversity shell beds are excellent examples of multiple-event carbonate deposits generated in a siliciclastic-dominated, restricted epeiric sea, revealing high-frequency cycles in proximal to distal restricted marine settings.Item Using detrital zircon and rutile to constrain sedimentary provenance of Early Paleozoic fluvial systems of the Araripe Basin, Western Gondwana.(2022) Cerri, Rodrigo Irineu; Warren, Lucas Veríssimo; Spencer, Christopher J.; Varejão, Filipe Giovanini; Promenzio, Paloma; Luvizotto, George Luiz; Assine, Mario LuisThe Early Paleozoic of the NE Brazilian sedimentary basins are key to understanding the primeval depositional environments and paleogeography of Western Gondwana after its final assembly. In this context, determining the sedimentary provenance of the Early Paleozoic Cariri Formation (basal unit of the Araripe Basin) may improve paleogeographic reconstructions and stratigraphic correlations. Despite the Araripe Basin being one of the best-studied interior basins of northeastern Brazil, the Cariri Formation lacks detailed geochronological and sedimentary provenance analyses, which hamper precise definitions of its depositional age, sedimentary source areas and paleogeography. Considering this scenario, we performed a combined multiproxy approach, including sedimentologic and stratigraphic analysis, detrital zircon U–Pb dating and provenance studies based on trace elements in detrital rutile. The maximum depositional age for the Cariri Formation suggests that its sedimentation started after the Late Cambrian. Detrital zircon ages and detrital rutile provenance indicate that the primary source areas for the Cariri Formation fluvial system were the orogenic terranes related to the Brasiliano Orogeny, located at the SE of the Borborema Province (e.g., Sergipano Belt), with secondary, but also important, the contribution of Cambrian sources. Records of this event are also found in northern Africa, where units related to the Neoproterozoic East African-Antarctic and Pan African orogens provided sediments for basin-scale fluvial systems.Item Unravelling the protracted U-Pb zircon geochronological record of high to ultrahigh temperature metamorphic rocks : Implications for provenance investigations.(2023) Tedeschi, Mahyra; Vieira, Pedro Leonardo Rossi; Amaral, Matheus Henrique Kuchenbecker do; Ribeiro, Bruno Vieira; Barrote, Vitor Rodrigues; Reis, Humberto Luis Siqueira; Stutenbecker, Laura; Lana, Cristiano de Carvalho; Soares, Antônio Carlos Pedrosa; Dussin, Ivo AntonioThe assessment of detrital zircon age records is a key method in basin analysis, but it is prone to several biases that may compromise accurate sedimentary provenance investigations. High to ultrahigh temperature (HT-UHT) metamorphism (especially if T > 850 °C) is herein presented as a natural cause of bias in provenance studies based on U-Pb detrital zircon ages, since zircon from rocks submitted to these extreme and often prolonged conditions frequently yield protracted, apparently concordant, geochronological records. Such age spreading can result from disturbance of the primary U-Pb zircon system, likewise from (re)crystallization processes during multiple and/or prolonged metamorphic events. In this contribution, available geochronological data on Archean, Neoproterozoic and Palaeozoic HT-UHT metamorphic rocks, acquired by different techniques (SIMS and LA-ICP-MS) and showing distinct compositions, are reassessed to demonstrate HT-UHT metamorphism may result in modes and age distributions of unclear geological meaning. As a consequence, it may induce misinterpretations on U-Pb detrital zircon provenance analyses, particularly in sedimentary rocks metamorphosed under such extreme temperature conditions. To evaluate the presence of HT-UHT metamorphism-related bias in the detrital zircon record, we suggest a workflow for data acquisition and interpretation, combining a multi-proxy approach with: (i) in situ U-Pb dating coupled with Hf analyses to retrieve the isotopic composition of the sources, and (ii) the integration of a petrochronological investigation to typify fingerprints of the HT-UHT metamorphic event. The proposed workflow is validated in the investigation of one theoretical and one natural example allowing a better characterization of the sedimentary sources, maximum depositional ages, and the tectonic setting of the basin. Our workflow allows to the appraisal of biases imposed by HT-UHT metamorphism and resulting disturbances in the U-Pb detrital zircon record, particularly for sedimentary rocks that underwent HT-UHT metamorphism and, finally, suggests ways to overcome these issues.Item Application of multivariate statistic of U, Th and Pb concentrations and Pb Isotopic signatures in the assessment of geogenic and anthropogenic sources in a U-mineralized area.(2019) Vecchia, Adriana Monica Dalla; Lena, Jorge Carvalho de; Ladeira, Ana Cláudia QueirozThis work presents a Principal Component Analysis (PCA) study using Pbi- sotope signatures and U, Th and Pb concentrations from groundwater, sedi- ments and rocks (granites and orthogneisses) of the Complex of Lagoa Real (Bahia, Brazil). This area is naturally enriched in U and Th, with the occur- rence of Pb derived from the radioactive decay of the elements (238U, 235U and 232Th) in the form of their stable isotopes 206Pb, 207Pb and 208Pb in addition to the natural isotope 204Pb. Sampling was carried out in the rainy season (De- cember to January) and the points were selected according to regional hy- drology and geology. Thirty samples were analyzed: 12 of groundwater (AP) and 18 of sediments (S). The results show that the use of isotopic ratios allows discrimination between geogenic and anthropogenic samples. This informa- tion is not obtained using only the analysis of concentration data. Statistically, the isotopic data of Pb stand out as an efficient tool in the characterization of sources in the scenario investigated, allowing an effective environmental monitoring and a better management of the mining activities.Item Geochemical evolution of soils developed from pyroclastic rocks of Trindade Island, South Atlantic.(2021) Mateus, Ana Carolina Campos; Varajão, Angélica Fortes Drummond Chicarino; Oliveira, Fábio Soares de; Petit, Sabine; Schaefer, Carlos Ernesto Gonçalves ReynaudThe geochemical behavior of the major, minor, trace and rare earths elements (REEs) in soil profiles from ultramafic volcanoclastic rocks of the Vulcão do Paredão and Morro Vermelho Formation from Trindade Island (TI) was analyzed in this study. Losses and gains of chemical elements were calculated through the mass balance for two profiles along the slope: one located at higher altitude (460 m) and the other at lower altitude (258 m). In all profiles, Al, Fe and Ti accumulate due to their low mobility, whereas Ca, Na, K and Mg are the most intensely leached. Soils located at lower altitude show higher K and Mg values in the surface due to the contribution of saline sprays. Leaching of the REEs from higher to the lower slope led to the enrichment of these elements, especially the light REEs, in the soil at the lowest altitude (258 m). The high altitude profile showed Ce positive anomaly due to longer exposure to weathering. The geochemical balance shows a relative enrichment of Ti, Mn, Fe, Co, Cr, Ni, V, Zr, S related to the loss of mobile elements during the soil formation process, despite the youthful nature of these volcanic rocks.Item Non-allophanic Andosols of Trindade Island, south Atlantic : a new soil order in Brazil.(2020) Mateus, Ana Carolina Campos; Varajão, Angélica Fortes Drummond Chicarino; Oliveira, Fábio Soares de; Petit, Sabine; Schaefer, Carlos Ernesto Gonçalves ReynaudThe pedological studies carried out so far in Trindade Island (TI) have obtained patchy evidences of allophane, without detailed mineralogical and micromorphological studies to confirm the occurrence of Andosols in TI. Therefore, in this study, the mineralogical, micromorphological, physical and chemical characterization of four soil profiles from Vulcão do Paredão (P1) and Morro Vermelho formations (P2, P3, and P4) were carried on the latest volcanic events in Brazil from Trindade Island (TI) with the aim of to evaluate the presence of Andosols in this oceanic island. Profiles P1 and P2 are developed on pyroclastic bombs, and show, respectively, A-Bi- C and decapitated A-C horizons, whereas P3 and P4 are developed on lapillitic and bomb pyroclasts, show A-C horizons. The soil profiles have a reddish and brownish clayey matrix, are highly friable and show a plastic consistency. Their microstructures are granular, single grain and intergrain microaggregate, in which aggregates display an undifferentiated b-fabric. The mineralogical constituents of the bulk fraction are biotite, hematite, magnetite, ilmenite, pyroxene, olivine, halloysite, goethite, anatase, and rutile. The clay fraction is marked by the presence of halloysite, ferrihydrite, and little amounts of allophane. All soils presented andic properties and can be classified as non-allophanic Andosols. In addition, micromorphological features closely resemble those reported in Andosols from other volcanic islands from elsewhere. The predominance of halloysite in the clay fraction formed by alteration of sideromelane, suggests that allophane would be an intermediate phase of this rapid transformation favored by the wet climate conditions of the highest parts of TI.