Use este identificador para citar ou linkar para este item: http://www.repositorio.ufop.br/jspui/handle/123456789/4974
Título: Magnesium oxide prepared via metal–chitosan complexation method : application as catalyst for transesterification of soybean oil and catalyst deactivation studies.
Autor(es): Almerindo, Gizelle Inácio
Probst, Luiz Fernando Dias
Campos, Carlos Eduardo Maduro de
Almeida, Rusiene Monteiro de
Meneghetti, Simoni Margareti Plentz
Meneghetti, Mario Roberto
Clacens, Jean-Marc
Fajardo, Humberto Vieira
Palavras-chave: Magnesium oxide
Chitosan
Ethanol
Biodiesel
Data do documento: 2011
Referência: ALMERINDO, G. I. et al. Magnesium oxide prepared via metal–chitosan complexation method: application as catalyst for transesterification of soybean oil and catalyst deactivation studies. Journal of Power Sources, v. 196, p. 8057-8063, 2011. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0378775311009967>. Acesso em: 02 fev. 2015.
Resumo: A simple method to prepare magnesium oxide catalysts for biodiesel production by transesterification reaction of soybean oil with ethanol is proposed. The method was developed using a metal–chitosan complex. Compared to the commercial oxide, the proposed catalysts displayed higher surface area and basicity values, leading to higher yield in terms of fatty acid ethyl esters (biodiesel). The deactivation of the catalyst due to contact with CO2 and H2O present in the ambient air was verified. It was confirmed that the active catalytic site is a hydrogenocarbonate adsorption site.
URI: http://www.repositorio.ufop.br/handle/123456789/4974
DOI: https://doi.org/10.1016/j.jpowsour.2011.05.030
ISSN: 0378-7753
Licença: O periódico Journal of Power Sources concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3580760453838
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